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Friday, 31 May 2013

PV energy is 40 times more efficient than the best bio-fuels_"Let the sun shine"- on INNOVATIONS!

In his paper in the magazine bioplastics entitled "From the (agricultural) field to the (car) wheel"
Michael Carus, Managing Director of the nova-Institute Hürth Germany attempts to answer the following 
Millennium class questions: " What will be the future of mobility?" and "Which solution is both land-efficient
and sustainable?"

On the one hand Biofuel (photosynthesis based) candidates are biodiesel,bioethanol, BTL 
(biomass to liquid) and on the other is PV-photovoltaic which they call "e-mobility.

In this work they compare land efficiency (average energy yield per hectare for different biofuels
with that of a solar driven electric car hence the title of their article 
"from the agricultural field to the car wheel"

Naturally German conditions are used but the author argues that there is little difference 
compared to other regions. He explains this in simple terms

The energy figures for both approaches are listed for easy comparison.

The full article may be found at the following link:

From the field to the wheel_Feb 17, 2012

PS "Is there any urgent need need for shale gas and oil via fracking?" Comments more than welcome.

Wednesday, 29 May 2013

End-of-Life Tyres (ELTs). update and review by B. Messenger Editor of Waste Management World magazine

This article was my first choice to introduce readers to the Waste Management World magazine. Indeed it was not so long ago that local authorities in my region of France-La Nièvre voiced their concern about the problems caused by used tyres and their ever increasing stock piles.

TACKLING TYRE WASTE


Tackling Tyres
With the rapidly growing number of vehicles around the world, the disposal of end-of-life tyres is a growing issue. Often simply dumped by the million to pose a serious environmental, health and fire risk, the technology to recover higher value materials and energy from waste tyres is moving forward.

The recovery of energy and materials from used tyres is big business. According to a report by the World Business Council for Sustainable Development, in 2008 around one billion End-of-Life Tyres (ELTs) were being produced globally each year. A further four billion were estimated to be held in stockpiles and landfills. Around the world it is estimated that some 1.5 billion new tyres are produced annually.
Figures published by the U.S. Rubber Manufacturers Association estimate that the U.S. - the world's largest producer of ELTs - generated 291.8 million tyres in 2009. With an average weight of 33.4 pounds (15.1 kg) that equates to some 4.4 million tonnes. According to statistics published by the European Tyre & Rubber Manufacturers' Association (ETRMA), in 2010 Europe produced around 2.7 million tonnes of ELTs.

TRADITIONAL APPROACHES:
Using traditional recycling techniques, granulated rubber recovered from waste tyres can be used variously as an aggregate, in tiles, adhesives, asphalt, sports surfaces, and extruded rubber products, to name but a few of its uses. And in terms of energy recovery the natural rubber fraction of the tyre can be considered as a renewable energy source.



REASONS TO GET MORE TOP CHEMICAL ENGINEERS  MANAGERS INVOLVED. 
With so many ELTs being produced, as well as the huge stockpiles from the past, waste tyres pose many potential dangers. They can contaminate groundwater, harbour disease carrying mosquitoes in pooled water and they are not only flammable, but once ablaze, extremely difficult to extinguish.
Often the result of arson, fires at tyre dumps are not uncommon. In 1990 Hagersville, Ontario was the scene of one of the worst tyre fires in history. As a mechanised army of fire fighters struggled to gain control of the situation, for 17 days 14 million tyres packed onto the 11 acre site spewed toxic clouds of thick black smoke into the air.
According to the New York Times, in addition to the toxic fumes, around 158,000 gallons (600,000 litres) of oil was released by the melting rubber was collected from the site. Chemical pollutants, suspected to have been caused by the operation to extinguish the fire were also found in the aftermath of the blaze.
In a separate incident an underground dumpsite in Wales,[UK] thought to contain around 9 million tyres, burned for an astonishing 15 years following its ignition in 1989.

HOPE ON HAND-High Value Alternatives
While the recovery of rubber, steel and energy from a potentially hazardous waste stream is certainly a big improvement over the not too distant past, increasingly a number of projects around the world are looking to ELTs as a potential source of much higher value materials.
One example of this is Dynamic Energy Alliance Corporation (DEAC), which recently relocated its headquarters from Memphis Tennessee to Dallas, Texas. The company has initiated the prototype phase of a project to validate its patent pending technologies to extract high value organic compounds from waste tyres. DEAC's process involves using pyrolysis to process ELTs with the production not only of energy, but of five marketable products – recycled carbon black, pyrolysis oil, fuel and extracts, a high BTU gas and steel.
The process the company is developing melds two technologies that it recently acquired licenses for, the Terpen Kraftig (TKF) Fractionator and Pyrolytic Augmentation.
The Pyrolytic Augmentation technology includes a series of specialised chemical compounds, which when combined within a pyrolysis plant are intended to enable the decomposition of the tyres to occur at lower temperatures - which would be a critical energy-saving benefit.
According to DEAC, a reactor technology included in the license allows it to recover additional high value organic compounds during tyre processing by changing the chemical reaction that's part of the de-vulcanization process used to convert the tyres' rubber into valuable products.
"The intellectual property includes a class of catalysts new to this industry but with exciting potential to improve the economics of waste tyre processing," explains Dr. Earl Beaver, chief technology officer of DEAC.
"The lower temperature enabled through the catalysts should allow for lower energy costs, lower maintenance costs and higher outputs of the most valuable liquid products and carbon black from tyre pyrolysis," he continues.
The TKF Fractionator process will capture the friable materials in the pyrolysis oil and purify them into high value organic compounds used in the fragrance, cosmetic and solvent industries - without disturbing the oil's hydrocarbon market value.
According to the company, the TKF processes, as adapted to its specifications, would produce up to 20 individual components at purity levels that are in high demand.
The process would consist of a series of unit operations functioning at a narrow range of temperatures, pressures, and volumes – which DEAC anticipates to yield the separation needed to maintain the purity and value of the products. Some of the 20 materials would be made in high purity for use as feedstock for downstream products, while others would be synthetic versions of natural products such as flavours, extracts and essential oils.
While the technology is still in the prototype phase, Charles R. Cronin, Jr., DEAC's chairman, is confident: "We believe these combined processes have the potential to produce more energy than the sum of the energy used to make the original tyre plus the energy expended to recover the products. These technologies may have the ability to transform the waste tyre industry from a landfill or rubber products business into a specialty chemical business."
Cronin added that the additional value will soon be validated in a life cycle analysis.(LCA)

The Tygre Project

is an EU project and consortium involving a number of commercial and academic European organisations

PYReco

Based in Redcar in the North East of England, PYReco is planning a facility which will use pyrolysis to breakdown tyres into high tensile steel, carbon black, diesel oil and syngas without producing any waste.





Conclusions


Ben Messenger, Managing Editor of WMW Magazine concludes: 
"While there are still some concerns surrounding illegal dumping or exporting of ELTs, the high recovery rates both in the U.S. and Europe are encouraging. However, in common with other waste streams, the greatest environmental and economic benefits from the treatment of ELTs lie furthest up the waste hierarchy.
Given the expanding global vehicle base, and the consumable nature of tyres, prevention is probably unattainable. Indeed, for the foreseeable future the number of waste tyres being generated globally will continue to grow. And for passenger car tyres, reuse options, such as retreading, are limited.
While the use of tyres as TDF is certainly better than landfilling or stockpiling, there are many interesting projects on the horizon which offer the potential of recovering not only energy or low value materials, but a wide range of high value materials and energy.
Around the world such projects are numerous. Not all will be commercially successful, but there are simply too many to think that none will make it. The date may not yet have been set, but the way in which waste tyres are treated looks set for a revolution."

High Purity Cr sources for Superalloys

Energy for th Future:Phil.Trans.A-Vol. 365, N° 1853 / April 15, 2007, curtesy The Royal Soc. London

Engineered foams and porous materials: Phil Trans A. Vol 364, N° 1838 / 06 curtesy_The R Soc. Lond